| Title: | Green methodology based on active air sampling followed by solid phase microextraction and gas chromatography-tandem mass spectrometry analysis to determine hazardous substances in different environments related to tire rubber |
| Author(s): | Armada D; Celeiro M; Dagnac T; Llompart M; |
| Address: | "CRETUS, Department of Analytical Chemistry, Nutrition and Food Science, Universidade de Santiago de Compostela, E-15782, Santiago de Compostela, Spain. Agronomic Research Centre (AGACAL-CIAM), Unit of Organic Contaminants, Apartado 10, E-15080, A Coruna, Spain. CRETUS, Department of Analytical Chemistry, Nutrition and Food Science, Universidade de Santiago de Compostela, E-15782, Santiago de Compostela, Spain. Electronic address: maria.llompart@usc.es" |
| DOI: | 10.1016/j.chroma.2022.462911 |
| ISSN/ISBN: | 1873-3778 (Electronic) 0021-9673 (Linking) |
| Abstract: | "A fast, efficient, and simple air sampling methodology was developed to study a high number of volatile and semivolatile organic compounds in air above tire rubber materials and surfaces made of recycled tire rubber. The proposed method, based on active sampling (solid-phase extraction, SPE) using a small quantity of sorbent material (25 mg) followed by solid-phase microextraction (SPME) and gas chromatography-tandem mass spectrometry analysis, was developed with the aim of determining 40 organics substances including polycyclic aromatic hydrocarbons (PAHs), plasticizers, antioxidants, and vulcanization agents. An experimental design was carried out to study the influence of main factors such as type of SPME fibre, solvent addition, headspace volume, stirring, as well as the factor interactions. Method performance showed good linearity in a broad concentration range (0.05 to 200 ng m(-3), for most compounds), with coefficients of determination (R(2)) higher than 0.9900. Whole method precision ( |
| Keywords: | Gas Chromatography-Mass Spectrometry/methods Hazardous Substances/analysis *Rubber/chemistry *Solid Phase Microextraction/methods Tandem Mass Spectrometry Air analysis Crumb rubber Gas chromatography-tandem mass spectrometry Hazardous compounds Solid-phas; |
| Notes: | "MedlineArmada, Daniel Celeiro, Maria Dagnac, Thierry Llompart, Maria eng Netherlands 2022/03/07 J Chromatogr A. 2022 Apr 12; 1668:462911. doi: 10.1016/j.chroma.2022.462911. Epub 2022 Feb 24" |
