Title: | "Pheromone syntheses: a tropical approach. Enantioselective synthesis of the (2R,6S,10S) and (2S,6S,10S) isomers of methyl 2,6,10-trimethyldodecanoate" |
Address: | "Laboratorio de Sintese de Produtos Naturais, Departamento de Quimica, Universidade Federal de Sao Carlos, Sao Carlos-SP, Brazil" |
DOI: | 10.1016/0968-0896(96)00015-6 |
ISSN/ISBN: | 0968-0896 (Print) 0968-0896 (Linking) |
Abstract: | "The enantioselective syntheses of two stereoisomers, (2R,6S,10S) and (2S,6S,10S), of methyl 2,6,10-trimethyldodecanote, out of eight possible isomers, are described , employing the stereoselective hydroboration of (-)-isopulegol (2) and (+)-neo-isopulegol (2a) as the key reaction" |
Keywords: | "Animals Insecta/*chemistry Laurates/*chemical synthesis Magnetic Resonance Spectroscopy Male Sex Attractants/*chemical synthesis Spectrophotometry, Infrared Stereoisomerism;" |
Notes: | "MedlineFerreira, J T Zarbin, P H eng Research Support, Non-U.S. Gov't England 1996/03/01 Bioorg Med Chem. 1996 Mar; 4(3):381-8. doi: 10.1016/0968-0896(96)00015-6" |