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Z Naturforsch C J Biosci

Title:		"Synthesis of methyl 4-dihydrotrisporate B and methyl trisporate B, morphogenetic factors of Zygomycetes fungi"
Author(s):		Nakamura Y; Paetz C; Boland W;
Address:		"Max Planck Institute for Chemical Ecology, Department of Bioorganic Chemistry, Jena, Germany. Max Planck Institute for Chemical Ecology, Biosynthesis/NMR, Jena, Germany. Max Planck Institute for Chemical Ecology, Department of Bioorganic Chemistry, Hans-Knoll-Strasse 8, 07745 Jena, Germany"
Journal Title:		Z Naturforsch C J Biosci
Year:		2018
Volume:		73
Issue:		1-Feb
Page Number:		59 - 66
DOI:		10.1515/znc-2017-0148
ISSN/ISBN:		0939-5075 (Print) 0341-0382 (Linking)
Abstract:		"(9Z)-Methyl 4-dihydrotrisporate B and (9Z)-methyl trisporate B, pheromones of Zygomycetes fungi, have been synthesized using Stille cross-coupling from previously described cyclohexenone precursors. Conducting the coupling without protection groups allowed for a short and stereospecific synthesis route of the late trisporoids. Stability studies for both the compounds revealed (9Z)-methyl trisporate B to be very unstable against UV irradiation"
Keywords:		"Carotenoids/*chemical synthesis Cyclohexenes/*chemical synthesis Fatty Acids, Unsaturated/*chemical synthesis Fungi, Unclassified/*chemistry/metabolism Mating Factor/*chemical synthesis/radiation effects Terpenes/*chemical synthesis Ultraviolet Rays Still;"
Notes:		"MedlineNakamura, Yoko Paetz, Christian Boland, Wilhelm eng Germany 2017/11/22 Z Naturforsch C J Biosci. 2018 Jan 26; 73(1-2):59-66. doi: 10.1515/znc-2017-0148"