Title: | Total synthesis of (-)-cephalosporolide D |
Author(s): | Kalavakuntla C; Kummari VB; Yadav JS; |
Address: | "Centre for Semiochemicals Division, CSIR-Indian Institute of Chemical Technology, Hyderabad, India. School of Science, Indrashil University, Ahmedabad, India" |
DOI: | 10.1080/14786419.2021.1896509 |
ISSN/ISBN: | 1478-6427 (Electronic) 1478-6419 (Linking) |
Abstract: | "In this communication, a concise and efficient synthetic route for the synthesis of (-)-Cephalosporolide D in enantioselective way has been described. In this synthesis, Mitsunobu esterification and Ring Closing Metathesis (RCM) for macrocyclic ring formation have been applied as key steps" |
Keywords: | Cyclization *Lactones (-)-Cephalosporolide D Barbier allylation Mitsunobu esterification Ring Closing Metathesis (RCM); |
Notes: | "MedlineKalavakuntla, Chiranjeevi Kummari, Vijaya Babu Yadav, Jhillu Singh eng England 2021/03/16 Nat Prod Res. 2022 Aug; 36(15):4021-4025. doi: 10.1080/14786419.2021.1896509. Epub 2021 Mar 15" |