Title: | Microwave-Assisted Catalytic Combustion for the Efficient Continuous Cleaning of VOC-Containing Air Streams |
Author(s): | Nigar H; Julian I; Mallada R; Santamaria J; |
Address: | "Nanoscience Institute of Aragon and Chemical and Environmental Engineering Department , University of Zaragoza , 50018 Zaragoza , Spain. Networking Research Centre CIBER-BBN , 28029 Madrid , Spain" |
ISSN/ISBN: | 1520-5851 (Electronic) 0013-936X (Linking) |
Abstract: | "A microwave-heated adsorbent-reactor system has been used for the continuous cleaning of air streams containing n-hexane at low concentrations. Both, a single catalytic bed (PtY zeolite) and a double (adsorptive DAY zeolite + catalytic PtY zeolite) fixed-bed reactor configurations were studied under dry and humid conditions. The zeolites were selectively heated by short periodic microwave pulses that caused the desorption of n-hexane and its subsequent catalytic combustion. The double bed configuration was attractive because it allowed nearly the same performance with only half of the catalyst load. The operation was especially efficient under realistic humid gas conditions that favored more intense microwave absorption, producing a faster heating of the adsorptive and catalytic beds. Under these conditions, continuous gas cleaning could be achieved with short (3 min, 30 W) microwave heating pulses every 5 min" |
Keywords: | Adsorption Catalysis Microwaves *Volatile Organic Compounds *Zeolites; |
Notes: | "MedlineNigar, Hakan Julian, Ignacio Mallada, Reyes Santamaria, Jesus eng Research Support, Non-U.S. Gov't 2018/04/18 Environ Sci Technol. 2018 May 15; 52(10):5892-5901. doi: 10.1021/acs.est.8b00191. Epub 2018 Apr 25" |