Title: | Extractive FTIR spectroscopy with cryogen-free low-temperature inert preconcentration for autonomous measurements of atmospheric organics: 1: Instrument development and preliminary performance |
Author(s): | Buckley PI; Bowdle DA; Newchurch MJ; Sive BC; Mount GH; |
ISSN/ISBN: | 1539-4522 (Electronic) 1559-128X (Linking) |
Abstract: | "In collaboration with the Jefferson County Department of Health and the Environmental Protection Agency (EPA), the University of Alabama in Huntsville developed a novel sensor for detecting very low levels of volatile organic compounds (VOCs). This sensor uses a commercial Fourier-transform infrared (FTIR) spectrometer, a commercial long-path IR gas cell, a commercial acoustic Stirling cyrocooler, and a custom cryogen-free cryotrap to improve sensitivity in an autonomous system with on-board quality control and quality assurance. Laboratory and initial field results show this methodology is sensitive to and well-suited for a wide variety of VOC atmospheric research and monitoring applications, including EPA National Air Toxics Trends Stations and the National Core monitoring network" |
Keywords: | "Acrolein/chemistry Air Pollutants/*analysis Alabama Algorithms *Atmosphere Calibration Chromatography, Gas Environmental Monitoring/*instrumentation Equipment Design Optical Phenomena Quality Control Software Spectrophotometry/methods Spectroscopy, Fourie;" |
Notes: | "MedlineBuckley, Patrick I Bowdle, David A Newchurch, M J Sive, Barkley C Mount, George H eng Research Support, U.S. Gov't, Non-P.H.S. 2015/05/15 Appl Opt. 2015 Apr 1; 54(10):2908-21. doi: 10.1364/AO.54.002908" |