Title: | "Isolation, Structure Elucidation, and Total Synthesis of Dolichovespulide, a Sesquiterpene from Dolichovespula Yellowjackets" |
Author(s): | Ren W; Gries R; Kurita KL; McCaughey CS; Alamsetti SK; Linington RG; Gries G; Britton R; |
Address: | "Department of Chemistry , Simon Fraser University , Burnaby , British Columbia V5A 1S6 , Canada. Department of Biological Sciences , Simon Fraser University , Burnaby , British Columbia V5A 1S6 , Canada" |
DOI: | 10.1021/acs.jnatprod.9b00238 |
ISSN/ISBN: | 1520-6025 (Electronic) 0163-3864 (Linking) |
Abstract: | "As part of an ongoing program to identify sex attractant pheromone components that mediate sexual communication in yellowjacket wasps, a novel sesquiterpene was isolated from body surface extracts of virgin bald-faced hornet queens, Dolichovespula maculata. The gross structure of this sesquiterpene was proposed through microscale spectroscopic analyses, and the configuration of the central olefin was subsequently confirmed by total synthesis. This new natural product (termed here dolichovespulide) represents an important addition to the relatively small number of terpenoids reported from the taxonomic insect family Vespidae" |
Keywords: | "Animals Chromatography, High Pressure Liquid Molecular Structure Spectrum Analysis/methods Wasps/*chemistry;" |
Notes: | "MedlineRen, Weiwu Gries, Regine Kurita, Kenji L McCaughey, Catherine S Alamsetti, Santosh K Linington, Roger G Gries, Gerhard Britton, Robert eng Research Support, Non-U.S. Gov't 2019/06/28 J Nat Prod. 2019 Jul 26; 82(7):2009-2012. doi: 10.1021/acs.jnatprod.9b00238. Epub 2019 Jun 18" |