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Int J Biol Macromol

Title:		Cellulose acetate/MOF film-based colorimetric ammonia sensor for non-destructive remote monitoring of meat product spoilage
Author(s):		Hashemian H; Ghaedi M; Dashtian K; Mosleh S; Hajati S; Razmjoue D; Khan S;
Address:		"Chemistry Department, Yasouj University, Yasouj 75918-74831, Iran. Chemistry Department, Yasouj University, Yasouj 75918-74831, Iran. Electronic address: m_ghaedi@mail.yu.ac.ir. Department of Chemistry, Iran University of Science and Technology, Tehran, Iran. Electronic address: kdasht68@gmail.com. Polymer Engineering Department, Faculty of Gas and Petroleum, Yasouj University, Gachsaran, Iran. Department of Semiconductors, Materials and Energy Research Center (MERC), P.O. Box 31787-316, Tehran, Iran. Medicinal Plants Research Center, Yasuj University of Medical Sciences, Yasuj, Iran. Department of Chemistry, University of Malakand, Chakdara, Khyber Pakhtunkhwa, Pakistan"
Journal Title:		Int J Biol Macromol
Year:		2023
Volume:		20230730
Issue:
Page Number:		126065 -
DOI:		10.1016/j.ijbiomac.2023.126065
ISSN/ISBN:		1879-0003 (Electronic) 0141-8130 (Linking)
Abstract:		"Herein, we designed an on-site and portable colorimetric assay using cellulose acetate polymeric films incorporated with HKUST-1 metal-organic framework while immersed in a solution of methyl red and brilliant cresyl blue organic dyes as an indicator for monitoring ammonia levels. Ammonia serves as a significant biomarker of food spoilage which falls under the category of volatile organic compounds (VOCs). The designed colorimetric solid-state sensor was comprehensively characterized using FE-SEM, EDS-mapping, XRD, FTIR, and contact angle analyses. The results confirmed the superior stability, water permeability, good crystallinity and desirable morphology of the prepared sensor platform. Additionally, customized smartphone was developed and applied for online signaling and colorimetric analysis. The findings demonstrated two linear ranges: 1-100 ppb and 0.1-1340 ppm with a detection limit of 0.02 ppm. The solid-state sensor exhibited high selectivity in the presence of other VOCs such as methanol, ethanol, acetone, 2-propanol, toluene, humidity, and hexane. It displayed acceptable repeatability in both inter-day (RSD = 3.38 %) and intraday (RSD = 3.86 %), long-term stability over 4 days as well as reusability over 3 cycles. We successfully applied this sensing platform for ammonia monitoring in spoiled meat foods including veal, fish and chicken. The results indicated favorable percentage recovery and repeatability, confirming the feasibility and potential applicability of this intelligent packaging system for monitoring freshness. The platform allows for real-time monitoring and data analysis via smartphone-based online signaling, providing a convenient and effective method for ensuring food quality"
Keywords:		Ammonia VOC Intelligent food packaging Metal-organic framework On-site colorimetric sensor Smartphone platform;
Notes:		"PublisherHashemian, Habibeh Ghaedi, Mehrorang Dashtian, Kheibar Mosleh, Soleiman Hajati, Shaaker Razmjoue, Damoun Khan, Sikandar eng Netherlands 2023/08/01 Int J Biol Macromol. 2023 Sep 30; 249:126065. doi: 10.1016/j.ijbiomac.2023.126065. Epub 2023 Jul 30"