Title: | Stereodivergent synthesis of (+)- and (-)-isolineatin |
Author(s): | Perez L; Alibes R; de March P; Busque F; Figueredo M; Font J; |
Address: | "Departament de Quimica, Universitat Autonoma de Barcelona, 08193 Bellaterra, Spain" |
ISSN/ISBN: | 1520-6904 (Electronic) 0022-3263 (Linking) |
Abstract: | A stereodivergent approach to (+)- and (-)-isolineatin using (S)-4-methyl-5-pivaloyloxymethyl-2(5H)-furanone as the single source of asymmetry by exploiting the inherent chirality at the C-5 stereocenter is described |
Keywords: | Furans/*chemistry Magnetic Resonance Spectroscopy Molecular Structure Pheromones/*chemical synthesis/chemistry Pyrans/*chemical synthesis/chemistry Stereoisomerism; |
Notes: | "MedlinePerez, Laura Alibes, Ramon de March, Pedro Busque, Felix Figueredo, Marta Font, Josep eng Research Support, Non-U.S. Gov't 2013/04/16 J Org Chem. 2013 May 3; 78(9):4483-9. doi: 10.1021/jo400487y. Epub 2013 Apr 22" |