| Title: | Simple Ion-Gas Mixtures as a Source of Key Molecules Relevant to Prebiotic Chemistry |
| Author(s): | Paula S; Goulding LS; Robertson KN; Clyburne JAC; |
| Address: | "Department of Chemistry, Saint Mary's University, Halifax, NS B3H 3C3, Canada" |
| DOI: | 10.3390/molecules26237394 |
| ISSN/ISBN: | 1420-3049 (Electronic) 1420-3049 (Linking) |
| Abstract: | "Very simple chemistry can result in the rapid and high-yield production of key prebiotic inorganic molecules. The two reactions investigated here involve such simple systems, (a) carbon disulfide (CS(2)) and acetate (CH(3)COO ) and (b) sulfur dioxide (SO(2)) and formate (HCOO ). They have been carried out under non-aqueous conditions, either in an organic solvent or with a powdered salt exposed to the requisite gas. Under such dry conditions the first reaction generated the thioacetate anion [CH(3)COS] while the second produced the radical [SO(2)(.)] anion. Anhydrous conditions are not rare and may have arisen on the early earth at sites where an interface between different phases (liquid/gas or solid/gas) could be generated. This is one way to rationalize the formation of molecules and ions (such as we have produced) necessary in the prebiotic world. Interpretation of our results provides insight into scenarios consistent with the more prominent theories of abiogenesis" |
| Keywords: | Epr abiogenesis hydrothermal systems inorganic chemistry interface main group chemistry membrane origins of life prebiotic radical anion small molecule activation volatile sulfur compounds wet dry cycle; |
| Notes: | "PubMed-not-MEDLINEPaula, Samuel Goulding, Liam S Robertson, Katherine N Clyburne, Jason A C eng RGPIN-2016-04204/Natural Sciences and Engineering Research Council/ Switzerland 2021/12/11 Molecules. 2021 Dec 6; 26(23):7394. doi: 10.3390/molecules26237394" |
