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Nanoscale


Title:Porous SnO2 nanospheres as sensitive gas sensors for volatile organic compounds detection
Author(s):Li Z; Zhao Q; Fan W; Zhan J;
Address:"Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Department of Chemistry, Shandong University, Jinan, 250100, Shandong, PR China"
Journal Title:Nanoscale
Year:2011
Volume:20110131
Issue:4
Page Number:1646 - 1652
DOI: 10.1039/c0nr00728e
ISSN/ISBN:2040-3372 (Electronic) 2040-3364 (Linking)
Abstract:"Porous SnO(2) nanospheres with high surface areas have been synthesized through a solvothermal method in the absence of any templates. The structure and morphology of the resultant products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and nitrogen adsorption-desorption technique. The as-prepared SnO(2) porous nanospheres with the diameters ranging from 90-150 nm are composed of small nanocrystals with average sizes of less than 10 nm. Results demonstrated that the formation of porous SnO(2) nanospheres is ascribed to etching the center part of the nanospheres. It was found that hydrochloric acid and NaClO played important roles in determining the final morphologies of the porous SnO(2) nanospheres. The gas sensing properties of the as-prepared porous SnO(2) nanospheres were investigated. By the comparative gas sensing tests, the porous SnO(2) nanospheres exhibited a superior gas sensing performance toward ppb level 2-chloroethanol and formaldehyde vapor, implying promising applications in detecting toxic volatile organic compounds (VOCs)"
Keywords:Equipment Design Equipment Failure Analysis Gases/analysis/chemistry Nanospheres/*chemistry/ultrastructure Tin Compounds/*chemistry *Transducers Volatile Organic Compounds/*analysis/chemistry;
Notes:"MedlineLi, Zhipeng Zhao, Quanqin Fan, Weiliu Zhan, Jinhua eng Research Support, Non-U.S. Gov't England 2011/02/01 Nanoscale. 2011 Apr; 3(4):1646-52. doi: 10.1039/c0nr00728e. Epub 2011 Jan 31"

 
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