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Arch Pharm Res

Title:		A versatile synthetic approach to grandisol monoterpene pheromone
Author(s):		Han YT; Kim NJ; Jung JW; Yun H; Lee S; Suh YG;
Address:		"College of Pharmacy, Seoul National University, Seoul 151-742, Korea"
Journal Title:		Arch Pharm Res
Year:		2011
Volume:		20111006
Issue:		9
Page Number:		1437 - 1442
DOI:		10.1007/s12272-011-0904-7
ISSN/ISBN:		1976-3786 (Electronic) 0253-6269 (Linking)
Abstract:		"A versatile and efficient synthetic procedure for the grandisol pheromone library has been established. The key feature of our synthesis involves a versatile and highly regioselective Pd(0)-catalyzed intramolecular allylic alkylation for the key cyclobutane skeleton of grandisol. In this connection, the concise synthesis of (+/-)-grandisol as well as mechanism study of Pd(0)-catalyzed regioselective cyclization as a key reaction have also been accomplished"
Keywords:		Alkylation Catalysis Cyclization Molecular Structure Palladium/chemistry Sex Attractants/*chemical synthesis/chemistry/pharmacology Stereoisomerism Terpenes/*chemical synthesis/chemistry/pharmacology Volatilization;
Notes:		"MedlineHan, Young Taek Kim, Nam-Jung Jung, Jong-Wha Yun, Hwayoung Lee, Sujin Suh, Young-Ger eng Research Support, Non-U.S. Gov't Korea (South) 2011/10/07 Arch Pharm Res. 2011 Sep; 34(9):1437-42. doi: 10.1007/s12272-011-0904-7. Epub 2011 Oct 6"