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Chem Commun (Camb)

Title:		Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds
Author(s):		Braga D; Maini L; Polito M; Mirolo L; Grepioni F;
Address:		"Dipartimento di Chimica G. Ciamician, Universita di Bologna, Via Selmi 2, 40126 Bologna, Italy. dbraga@ciam.unibo.it"
Journal Title:		Chem Commun (Camb)
Year:		2002
Volume:
Issue:		24
Page Number:		2960 - 2961
DOI:		10.1039/b209861j
ISSN/ISBN:		1359-7345 (Print) 1359-7345 (Linking)
Abstract:		"Solvent-free reactions with molecular systems have been exploited to prepare hybrid organic-organometallic solids: grinding of the complex [Fe(eta 5-C5H4COOH)2] with solid bases B generates quantitatively the corresponding hydrogen bonded salts [Fe(eta 5-C5H4COOH)(eta 5-C5H4COO)][HB] (B = 1,4-diazabicyclo[2.2.2]octane, 1,4-phenylenediamine); gas-solid reactions are also possible with volatile bases"
Keywords:
Notes:		"PubMed-not-MEDLINEBraga, Dario Maini, Lucia Polito, Marco Mirolo, Laurent Grepioni, Fabrizia eng England 2003/01/23 Chem Commun (Camb). 2002 Dec 21; (24):2960-1. doi: 10.1039/b209861j"