| Title: | Identifying Volatile Chemical Product Tracer Compounds in U.S. Cities |
| Author(s): | Gkatzelis GI; Coggon MM; McDonald BC; Peischl J; Aikin KC; Gilman JB; Trainer M; Warneke C; |
| Address: | "NOAA Chemical Sciences Laboratory, Earth System Research Laboratories, 325 Broadway, R/CSL7, Boulder, Colorado 80305, United States. Cooperative Institute for Research in Environmental Sciences, Boulder, Colorado 80309, United States" |
| ISSN/ISBN: | 1520-5851 (Electronic) 0013-936X (Linking) |
| Abstract: | "With traffic emissions of volatile organic compounds (VOCs) decreasing rapidly over the last decades, the contributions of the emissions from other source categories, such as volatile chemical products (VCPs), have become more apparent in urban air. In this work, in situ measurements of various VOCs are reported for New York City, Pittsburgh, Chicago, and Denver. The magnitude of different emission sources relative to traffic is determined by measuring the urban enhancement of individual compounds relative to the enhancement of benzene, a known tracer of fossil fuel in the United States. The enhancement ratios of several VCP compounds to benzene correlate well with population density (R(2) approximately 0.6-0.8). These observations are consistent with the expectation that some human activity should correlate better with the population density than transportation emissions, due to the lower per capita rate of driving in denser cities. Using these data, together with a bottom-up fuel-based inventory of vehicle emissions and volatile chemical products (FIVE-VCP) inventory, we identify tracer compounds for different VCP categories: decamethylcyclopentasiloxane (D5-siloxane) for personal care products, monoterpenes for fragrances, p-dichlorobenzene for insecticides, D4-siloxane for adhesives, para-chlorobenzotrifluoride (PCBTF) for solvent-based coatings, and Texanol for water-based coatings. Furthermore, several other compounds are identified (e.g., ethanol) that correlate with population density and originate from multiple VCP sources. Ethanol and fragrances are among the most abundant and reactive VOCs associated with VCP emissions" |
| Keywords: | *Air Pollutants/analysis Chicago Cities Environmental Monitoring Humans New York City United States Vehicle Emissions/analysis *Volatile Organic Compounds/analysis; |
| Notes: | "MedlineGkatzelis, Georgios I Coggon, Matthew M McDonald, Brian C Peischl, Jeff Aikin, Kenneth C Gilman, Jessica B Trainer, Michael Warneke, Carsten eng Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. 2020/12/17 Environ Sci Technol. 2021 Jan 5; 55(1):188-199. doi: 10.1021/acs.est.0c05467. Epub 2020 Dec 16" |
