| Title: | Preparation and application of multiple-component-doped keggin polyoxometalate microtubes--towards a component-tunable hollow structure |
| Author(s): | Shen Y; Peng J; Pang H; Zhang P; Chen D; Chen C; Zhang H; Meng C; Su Z; |
| Address: | "Key Laboratory of Polyoxometalate Science of Ministry of Education Faculty of Chemistry, Northeast Normal University, Changchun, Jilin, 130024, PR China" |
| ISSN/ISBN: | 1521-3765 (Electronic) 0947-6539 (Linking) |
| Abstract: | "In this paper, the preparation of ascorbic acid (AA)-doped polyoxometalate (SiW(12)-AA) microtubes is described. The SiW(12)-AA microtubes convert to heteropoly blue microtubes upon exposure to ammonia gas, which is an ammonia-triggered solid-solid redox reaction between AA molecules and polyoxometalates, and can possibly be applied to a chemical sensor for detecting ammonia and volatile organic amines. Furthermore, the SiW(12)-AA microtubes have been applied to the in situ synthesis of Ag nanoparticles (NPs) through the redox reaction between the AA component and Ag(+) ions occurring on the surfaces of the SiW(12)-AA microtubes to give silver NPs immobilized on polyoxometalate microtubes (Ag@SiW(12))" |
| Keywords: | "Ascorbic Acid/*chemistry Coloring Agents/*chemistry Metal Nanoparticles/*chemistry Models, Molecular Oxidation-Reduction Silver/*chemistry Tungsten Compounds/*chemical synthesis/*chemistry;" |
| Notes: | "MedlineShen, Yan Peng, Jun Pang, Haijun Zhang, Pengpeng Chen, Dan Chen, Changyun Zhang, Huanqiu Meng, Cuili Su, Zhongmin eng Research Support, Non-U.S. Gov't Germany 2011/02/24 Chemistry. 2011 Mar 21; 17(13):3657-62. doi: 10.1002/chem.201001837. Epub 2011 Feb 23" |
