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Environ Sci Technol


Title:Catalytic Control of Typical Particulate Matters and Volatile Organic Compounds Emissions from Simulated Biomass Burning
Author(s):Chen Y; Tian G; Zhou M; Huang Z; Lu C; Hu P; Gao J; Zhang Z; Tang X;
Address:"Institute of Atmosphere Sciences, Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science and Engineering, Fudan University , Shanghai 200433, China. School of Chemistry & Chemical Engineering, University of Jinan , Jinan, Shandong 250022, China. Collaborative Innovation Center of Atmospheric Environment and Equipment Technology (CICAEET) , Nanjing, Jiangsu 210044, China"
Journal Title:Environ Sci Technol
Year:2016
Volume:20160511
Issue:11
Page Number:5825 - 5831
DOI: 10.1021/acs.est.5b06109
ISSN/ISBN:1520-5851 (Electronic) 0013-936X (Linking)
Abstract:"Emissions of particulate matters (PMs) and volatile organic compounds (VOCs) from open burning of biomass often cause severe air pollution; a viable approach is to allow biomass to burn in a furnace to collectively control these emissions, but practical control technologies for this purpose are lacking. Here, we report a hollandite manganese oxide (HMO) catalyst that can efficiently control both typical PMs and VOCs emissions from biomass burning. The results reveal that typical alkali-rich PMs such as KCl particles are disintegrated and the K(+) ions are trapped in the HMO 'single-walled' tunnels with a great trapping capacity. The K(+)-trapping HMO increases the electron density of the lattice oxygen and the redox ability, thus promoting the combustion of soot PMs and the oxidation of typical VOCs such as aldehydes and acetylates. This could pave a way to control emissions from biomass burning concomitant with its utilization for energy or heat generation"
Keywords:Air Pollutants Air Pollution Biomass *Particulate Matter *Volatile Organic Compounds;
Notes:"MedlineChen, Yaxin Tian, Guangkai Zhou, Meijuan Huang, Zhiwei Lu, Chenxi Hu, Pingping Gao, Jiayi Zhang, Zhaoliang Tang, Xingfu eng Research Support, Non-U.S. Gov't 2016/04/30 Environ Sci Technol. 2016 Jun 7; 50(11):5825-31. doi: 10.1021/acs.est.5b06109. Epub 2016 May 11"

 
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