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J Chem Ecol


Title:Synthesis and field tests of possible minor components of the sex pheromone of Prionus californicus
Author(s):Maki EC; Rodstein J; Millar JG; Barbour KS; Hanks LM; Barbour JD;
Address:"Southwest Idaho Research & Extension Center, Parma, ID 83660-9637, USA"
Journal Title:J Chem Ecol
Year:2011
Volume:20110527
Issue:7
Page Number:714 - 716
DOI: 10.1007/s10886-011-9972-x
ISSN/ISBN:1573-1561 (Electronic) 0098-0331 (Linking)
Abstract:"Earlier work has shown that adult male Prionus californicus Motschulsky (Coleoptera: Cerambycidae) are attracted to the female-produced compound (3R,5S)-3,5-dimethyldodecanoic acid, and to a synthetic mixture of the four stereoisomers of 3,5-dimethyldodecanoic acid. Here, we report the results of field trials that tested whether or not three structurally related compounds (methyl 3,5-dimethyldodecanoate, 3,5-dimethyltridecanoic acid, and 3,5-dimethylpentadecanoic acid), present in extracts of virgin females, are attractive, and whether or not they influence attraction to 3,5-dimethyldodecanoic acid. In a trial with single components, only traps baited with the acid or its methyl ester captured more beetles than did control traps; catches to the acid were five times higher than to the methyl ester. Another trial, excluding 3,5-dimethyldodecanoic acid, confirmed the activity of the methyl ester. Finally, addition of the three compounds to 3,5-dimethyldodecanoic acid, in the ratio found in extracts from female beetles, gave a catch similar to that of traps baited with 3,5-dimethyldodecanoic acid alone. Consequently, the function of these minor compounds remains undetermined"
Keywords:"Animals Chromatography, Gas Coleoptera/*chemistry *Decanoic Acids/chemical synthesis/metabolism Female Male Sex Attractants/chemical synthesis/*chemistry/metabolism Solid Phase Microextraction Stereoisomerism;"
Notes:"MedlineMaki, Elin C Rodstein, Joshua Millar, Jocelyn G Barbour, Karen S Hanks, Lawrence M Barbour, James D eng Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. 2011/06/02 J Chem Ecol. 2011 Jul; 37(7):714-6. doi: 10.1007/s10886-011-9972-x. Epub 2011 May 27"

 
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