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Chem Commun (Camb)


Title:Self-aggregated phosphorescent platinum(II) polymeric material from modified poly(4-vinylpyridine)
Author(s):Kwok CC; Yu SC; Sham IH; Che CM;
Address:"Department of Chemistry and the HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong SAR, China"
Journal Title:Chem Commun (Camb)
Year:2004
Volume:20040927
Issue:21
Page Number:2512 - 2513
DOI: 10.1039/b409333j
ISSN/ISBN:1359-7345 (Print) 1359-7345 (Linking)
Abstract:"A solvochromic material made from incorporation of photoluminescent Pt(II)([formula: see text]) moieties into commercially available homopolymer poly(4-vinylpyridine) exhibits different emission energies, due to different degrees of self-aggregation in various solvents and as thin film upon exposure to vapour of different volatile organic compounds (VOC); self-aggregation enables intra- and intermolecular interactions arising from pi-stacking of the Pt([formula: see text]) moieties, which is affected by medium polarity"
Keywords:*Luminescent Measurements Micelles Molecular Structure Organometallic Compounds/*chemical synthesis Platinum/*chemistry Polyvinyls/*chemistry Solvents/chemistry;
Notes:"MedlineKwok, Chi-Chung Yu, Sze-Chit Sham, Iona H T Che, Chi-Ming eng Research Support, Non-U.S. Gov't England 2004/10/30 Chem Commun (Camb). 2004 Nov 7; (21):2512-3. doi: 10.1039/b409333j. Epub 2004 Sep 27"

 
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