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Biosci Biotechnol Biochem

Title:		"New synthesis of the (3Z,6Z,9S,10R)-isomers of 9,10-epoxy-3,6-henicosadiene and 9,10-epoxy-1,3,6-henicosatriene, pheromone components of the female fall webworm moth, Hyphantria cunea"
Author(s):		Nakanishi A; Mori K;
Address:		"Department of Applied Biological Chemistry, The University of Tokyo, Tokyo"
Journal Title:		Biosci Biotechnol Biochem
Year:		2005
Volume:		69
Issue:		5
Page Number:		1007 - 1013
DOI:		10.1271/bbb.69.1007
ISSN/ISBN:		0916-8451 (Print) 0916-8451 (Linking)
Abstract:		"(3Z,6Z,9S,10R)-9,10-Epoxy-3,6-henicosadiene (1) and (3Z,6Z,9S,10R)-9,10-epoxy-1,3,6-henicosatriene (5), pheromone components of the female fall webworm moth (Hyphantria cunea Drury), were synthesized by starting from (2S,3R)-2,3-epoxy-4-t-butyldimethylsilyloxy-1-butanol (8). Epoxide 8 was prepared by employing lipase-catalyzed asymmetric acetylation of (+/-)-8 as the key optical resolution step"
Keywords:		"Animals Epoxy Compounds/*chemical synthesis/chemistry Fatty Acids, Unsaturated/*chemical synthesis/chemistry Female Molecular Structure Moths/*chemistry Sex Attractants/*chemical synthesis/chemistry Stereoisomerism;"
Notes:		"MedlineNakanishi, Akira Mori, Kenji eng England 2005/05/26 Biosci Biotechnol Biochem. 2005 May; 69(5):1007-13. doi: 10.1271/bbb.69.1007"