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J Chem Ecol


Title:Insect sex pheromones: Determination of half-lives from formulations by collection of emitted vapor
Author(s):McDonough LM; Butler LI;
Address:"Yakima Agricultural Research Laboratory, Agric. Res. Serv., USDA, 98902, Yakima, Washington"
Journal Title:J Chem Ecol
Year:1983
Volume:9
Issue:11
Page Number:1491 - 1502
DOI: 10.1007/BF00988515
ISSN/ISBN:0098-0331 (Print) 0098-0331 (Linking)
Abstract:A new method for determining half-lives for the evaporation of sex pheromones from formulations has been developed. A previously unexploited mathematical relationship makes possible the determination of half-lives of over 1000 days by collecting evaporated pheromone for 1-4 hr and measuring the amount collected and the amount left in the formulation. Purified nitrogen flows over the test material and the evaporated pheromone is qualitatively collected on an adsorbent of 80-100 mesh silica gel silanized with octadecyltrichlorosilane. Quantitation is by gas chromatography. Quantitative mass balance was achieved and half-lives determined by this new method are in agreement with half-lives previously determined by measuring the amount of pheromone left in septa after a sequence of time intervals. Previously undetermined half-lives for acetates and alcohols are reported
Keywords:
Notes:"PubMed-not-MEDLINEMcDonough, L M Butler, L I eng 1983/11/01 J Chem Ecol. 1983 Nov; 9(11):1491-502. doi: 10.1007/BF00988515"

 
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