| Title: | Spatial Separation of the Conformers of Methyl Vinyl Ketone |
| Author(s): | Wang J; Kilaj A; He L; Dlugolecki K; Willitsch S; Kupper J; |
| Address: | "Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestrasse 85, 22607 Hamburg, Germany. Department of Chemistry, University of Basel, Klingelbergstrasse 80, 4056 Basel, Switzerland. Department of Physics, Universitat Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany. Center for Ultrafast Imaging, Universitat Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany" |
| ISSN/ISBN: | 1520-5215 (Electronic) 1089-5639 (Linking) |
| Abstract: | "Methyl vinyl ketone (C(4)H(6)O) is a volatile, labile organic compound of importance in atmospheric chemistry. We prepared a molecular beam of methyl vinyl ketone with a rotational temperature of 1.2(2) K and demonstrated the spatial separation of the s-cis and s-trans conformers of methyl vinyl ketone using the electrostatic deflector. The resulting sample density was 1.5(2) x 10(8) cm(-3) for the direct beam in the laser ionization region. These conformer-selected methyl vinyl ketone samples are well suited for conformer-specific chemical reactivity studies such as in Diels-Alder cycloaddition reactions" |
| Notes: | "PubMed-not-MEDLINEWang, Jia Kilaj, Ardita He, Lanhai Dlugolecki, Karol Willitsch, Stefan Kupper, Jochen eng 2020/09/11 J Phys Chem A. 2020 Oct 8; 124(40):8341-8345. doi: 10.1021/acs.jpca.0c05893. Epub 2020 Sep 28" |
