| Title: | Formation of organic chloramines during chlorination of 18 compounds |
| Author(s): | Guo Y; Yang Q; Xu J; Bai X; Han Q; Nie J; Zhang L; Li H; Gao H; Zhou W; Li J; |
| Address: | "Department of Applied Chemistry, China Agricultural University, Beijing 100193, PR China. Institute of Geographical Sciences, Henan Academy of Sciences, Zheng Zhou 450052, China. Department of Applied Chemistry, China Agricultural University, Beijing 100193, PR China. Electronic address: zhouwenfeng@cau.edu.cn. Department of Applied Chemistry, China Agricultural University, Beijing 100193, PR China. Electronic address: jli@cau.edu.cn" |
| DOI: | 10.1016/j.watres.2021.117570 |
| ISSN/ISBN: | 1879-2448 (Electronic) 0043-1354 (Linking) |
| Abstract: | "Organic chloramines have attracted considerable attention because of their potential toxicity and reactivity. However, the lack of suitable and effective analytical methods has limited the study of organic chloramines due to their volatile and unstable properties. In this study, membrane introduction mass spectrometry (MIMS) combined with DPD/FAS titration was used to monitor the formation of organic chloramines. N-chlorodimethylamine [(CH(3))(2)NCl] and N-chlorodiethylamine [(C(2)H(5))(2)NCl] were detected and identified as the dominant volatile DBPs during chlorination of 18 organic compounds with dimethylamine or diethylamine functional groups, with yields ranging from 0.3% to 51.1% at a chlorine to precursor (Cl/P) molar ratio of 8.0. (CH(3))(2)NBr was formed in the presence of bromide, while the formation of (CH(3))(2)NCl was decreased. The reaction of phenol with (CH(3))(2)NCl combined with theoretical calculations confirmed that the reactivity of (CH(3))(2)NCl was similar to that of monochloramine. Moreover, (CH(3))(2)NCl and (C(2)H(5))(2)NCl were observed at the ppb level during chlorination of actual water samples collected from different areas. The results suggest that (CH(3))(2)NCl and (C(2)H(5))(2)NCl are important organic chloramines during chlorination, which may lead to the occurrence of further oxidation reactions and promote the formation of other disinfection byproducts simultaneously and should be of concern" |
| Keywords: | "Chloramines Chlorine/analysis *Disinfectants Disinfection Halogenation *Water Pollutants, Chemical/analysis *Water Purification Chlorination Chlorodimethylamine Disinfection byproducts Organic chloramines;" |
| Notes: | "MedlineGuo, Yang Yang, Qian Xu, Jie Bai, Xueling Han, Qihuan Nie, Jie Zhang, Luo Li, Hongtao Gao, Haixiang Zhou, WenFeng Li, Jing eng England 2021/09/01 Water Res. 2021 Oct 1; 204:117570. doi: 10.1016/j.watres.2021.117570. Epub 2021 Aug 19" |
