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Org Lett

Title:		Cobalt-Bisoxazoline-Catalyzed Enantioselective Cross-Coupling of alpha-Bromo Esters with Alkenyl Grignard Reagents
Author(s):		Zhou Y; Wang L; Yuan G; Liu S; Sun X; Yuan C; Yang Y; Bian Q; Wang M; Zhong J;
Address:		"Department of Applied Chemistry, China Agricultural University, 2 West Yuanmingyuan Road, Beijing 100193, P. R. China"
Journal Title:		Org Lett
Year:		2020
Volume:		20200520
Issue:		11
Page Number:		4532 - 4536
DOI:		10.1021/acs.orglett.0c01557
ISSN/ISBN:		1523-7052 (Electronic) 1523-7052 (Linking)
Abstract:		"The first catalytic asymmetric Kumada cross-coupling of organic halides with alkenyl Grignard reagents has been developed. The reaction was promoted by the cobalt-bisoxazoline catalyst and afforded various alpha-alkyl-beta,gamma-unsaturated esters with excellent enantioselectivities and moderate to good yields (
Keywords:
Notes:		"PubMed-not-MEDLINEZhou, Yun Wang, Lifeng Yuan, Gucheng Liu, Shikuo Sun, Xiao Yuan, Chaonan Yang, Yuxiong Bian, Qinghua Wang, Min Zhong, Jiangchun eng Research Support, Non-U.S. Gov't 2020/05/21 Org Lett. 2020 Jun 5; 22(11):4532-4536. doi: 10.1021/acs.orglett.0c01557. Epub 2020 May 20"