« Previous AbstractFate of chlorinated fatty acids in migrating sockeye salmon and their transfer to arctic grayling    Next Abstract"Emission factors and source profiles of VOCs emitted from coke production in Shanxi, China" »

Molecules

Title:		Metal-Organic Framework Assembled on Oriented Nanofiber Arrays for Field-Effect Transistor and Gas Sensor-Based Applications
Author(s):		Mu J; Zhong X; Dai W; Pei X; Sun J; Zhang J; Luo W; Zhou W;
Address:		"Faculty of Materials Science and Chemistry, China University of Geosciences, 388 Lumo Road, Wuhan 430074, China"
Journal Title:		Molecules
Year:		2022
Volume:		20220325
Issue:		7
Page Number:		-
DOI:		10.3390/molecules27072131
ISSN/ISBN:		1420-3049 (Electronic) 1420-3049 (Linking)
Abstract:		"Metal-organic framework (MOF) films are essential for numerous sensor and device applications. However, metal-organic framework materials have poor machinability due to their predominant powder-like nature, and their presence as the active layer in a device can seriously affect the performance and utility of the device. Herein, active layers of field-effect transistor (FETs) devices and chemiresistor gas sensors with high performance were constructed by loading Cu(3)(HITP)(2) (HITP = 2,3,6,7,10,11-hexaiminotriphenylene) in situ-axial anchoring on oriented nanofiber arrays prepared via electrospinning. The strong interaction between polar groups on the polymer chains and metal ions promotes the nucleation of Cu(3)(HITP)(2), steric hindrance makes particles of Cu(3)(HITP)(2) with uniform size, morphology, and good crystallinity during nucleation by liquid phase epitaxial growth (LPE). Influences of differently-oriented Cu(3)(HITP)(2) NFAs-based FETs on the electrical properties were studied, optimally oriented Cu(3)(HITP)(2) NFAs-based FETs showed good mobility of 5.09 cm(2)/V.s and on/off ratio of 9.6 x 10(3). Moreover, excellent gas sensing response characteristics were exhibited in sensing volatile organic compounds (VOCs). Chemiresistor gas sensors with high response value, faster response and recovery are widely suited for VOCs. It brings new inspirations for the design and utilization of electrically conductive MOFs as an active layer for FETs and sensor units for chemiresistor gas sensors"
Keywords:		field-effect transistor gas sensor liquid epitaxial growth metal-organic frameworks oriented nanofiber arrays;
Notes:		"PubMed-not-MEDLINEMu, Jinlong Zhong, Xing Dai, Wei Pei, Xin Sun, Jian Zhang, Junyuan Luo, Wenjun Zhou, Wei eng No. 11975212/National Natural Science Foundation of China/ No. LQY19A050001/the Zhejiang Provincial Natural Science Foundation of China/ Switzerland 2022/04/13 Molecules. 2022 Mar 25; 27(7):2131. doi: 10.3390/molecules27072131"