Title: | "Sex pheromone biosynthesis in the female olive fruit-fly. Double labelling from [18O2]-dioxygen into 1,7-dioxaspiro[5.5]undecane" |
Author(s): | Fletcher MT; Mazomenos BE; Georgakopoulos JH; Konstantopoulou MA; Wood BJ; De Voss JJ; Kitching W; |
Address: | "Department of Chemistry, University of Queensland, Brisbane, Qld 4072, Australia" |
ISSN/ISBN: | 1359-7345 (Print) 1359-7345 (Linking) |
Abstract: | "The demonstration that both oxygen atoms of 1,7-dioxaspiro[5.5]undecane (1), the sex-pheromone of the female olive fly, originate from dioxygen, strongly implicates monooxygenase mediated processes in assembly of (1), and reveals unexpected complexity in the formation of its nine-carbon precursor" |
Keywords: | Animals Drosophila/*metabolism Female Isotope Labeling Oxygen/*metabolism Oxygen Isotopes Sex Attractants/*biosynthesis Spiro Compounds/*metabolism; |
Notes: | "MedlineFletcher, Mary T Mazomenos, Basilis E Georgakopoulos, John H Konstantopoulou, Maria A Wood, Barry J De Voss, James J Kitching, William eng Research Support, Non-U.S. Gov't England 2002/07/12 Chem Commun (Camb). 2002 Jun 21; (12):1302-3. doi: 10.1039/b202697j" |