| Title: | Cu-VWT Catalysts for Synergistic Elimination of NO(x) and Volatile Organic Compounds from Coal-Fired Flue Gas |
| Author(s): | Xiao G; Guo Z; Lin B; Fu M; Ye D; Hu Y; |
| Address: | "School of Environment and Energy, South China University of Technology, Guangzhou 510006, P. R. China. Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangzhou 510006, P. R. China. The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006, P. R. China" |
| ISSN/ISBN: | 1520-5851 (Electronic) 0013-936X (Linking) |
| Abstract: | "A dual-function catalyst, designated as Cu5-VWT, has been constructed for the synergistic removal of NO(x) and volatile organic compounds under complex coal-fired flue gas conditions. The removal of toluene, propylene, dichloromethane, and naphthalene all exceeded 99% (350 degrees C), and the catalyst could effectively block the generation of polycyclic aromatic hydrocarbons. Mechanistic studies have shown that Cu sites on the Cu5-VWT catalyst facilitate catalytic oxidation, while V sites facilitate NO(x) reduction. Thus, toluene oxidation and NO(x) reduction can proceed simultaneously. The removal of total hydrocarbons and nonmethane total hydrocarbons from 1200 m(3).h(-1) real coal-fired flue gas by a monolithic catalyst were determined as 92 and 96%, respectively, much higher than those of 54 and 72% over a commercial VWT catalyst, indicating great promise for industrial application" |
| Keywords: | Cu-VWT catalyst NOx and VOCs coal-fired flue gas synergistic removal; |
| Notes: | "PubMed-not-MEDLINEXiao, Gaofei Guo, Ziyang Lin, Beilong Fu, Mingli Ye, Daiqi Hu, Yun eng 2022/06/30 Environ Sci Technol. 2022 Jul 19; 56(14):10095-10104. doi: 10.1021/acs.est.2c02083. Epub 2022 Jun 29" |
