| Title: | Measurements of Activity Coefficients at Infinite Dilution for Organic Solutes in the Ionic Liquids N-Ethyl- and N-Octyl-N-methylmorpholinium Bis(trifluoromethanesulfonyl)imide. A Useful Tool for Solvent Selection |
| Author(s): | Marcinkowski L; Eichenlaub J; Ghasemi E; Polkowska Z; Kloskowski A; |
| Address: | "Department of Physical Chemistry, Faculty of Chemistry, Gdansk University of Technology, Narutowicza Str.11/12, 80-233 Gdansk, Poland. Department of Analytical Chemistry, Faculty of Chemistry, Gdansk University of Technology, Narutowicza Str.11/12, 80-233 Gdansk, Poland" |
| DOI: | 10.3390/molecules25030634 |
| ISSN/ISBN: | 1420-3049 (Electronic) 1420-3049 (Linking) |
| Abstract: | "In recent years, many papers describing ionic liquids (IL) as promising solvents in separation techniques have been published. The conscious choice of appropriate ionic liquid as absorption media in effective extraction of selected types of analytes requires deeper understanding of the analyte-IL interactions. Therefore, intensive research is conducted to determine the values of activity coefficient at infinite dilution, which allows us to characterize the nature of these interactions. Based on the inverse gas chromatography retention data, activity coefficients at infinite dilution gamma 13 infinity of 48 different organic compounds in the ionic liquids N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide [C(2)C(1)Mor][TFSI] and N-octyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide [C(8)C(1)Mor][TFSI] were determined. The measurements covered a broad range of volatile organic compounds, including n-alkanes, n-alkenes, n-alkynes, alcohols, aldehydes, ketones, aromatic compounds and common polar solvents, representing different types of interactions. Activity coefficients at infinite dilution were measured in the temperature range from 313.15 to 363.15 K. The excess partial molar enthalpies and entropies at infinite dilution were determined. Selectivity at infinite dilution was also calculated for exemplary separation processes in the hexane/benzene system. The obtained results were analyzed and compared with literature data for ionic liquids containing the same anion [TFSI] and different cations. The study results indicate that some potential applications of the investigated ionic liquids in separation problems exist" |
| Keywords: | "Algorithms Hydrocarbons, Fluorinated/*chemistry Imides/*chemistry Ionic Liquids/*chemistry *Models, Chemical Organic Chemicals/*chemistry Solutions Solvents/*chemistry activity coefficient at infinite dilution inverse gas chromatography ionic liquids morp;" |
| Notes: | "MedlineMarcinkowski, Lukasz Eichenlaub, Joachim Ghasemi, Elham Polkowska, Zaneta Kloskowski, Adam eng Switzerland 2020/02/07 Molecules. 2020 Feb 1; 25(3):634. doi: 10.3390/molecules25030634" |
