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Org Lett


Title:A general method for the synthesis of nonracemic trans-epoxides: concise syntheses of trans-epoxide-containing insect sex pheromones
Author(s):Kang B; Britton R;
Address:"Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia, V5A 1S6, Canada"
Journal Title:Org Lett
Year:2007
Volume:20071102
Issue:24
Page Number:5083 - 5086
DOI: 10.1021/ol702273n
ISSN/ISBN:1523-7060 (Print) 1523-7052 (Linking)
Abstract:"A general method for the synthesis of chiral nonracemic trans-epoxides has been developed that provides rapid access to alkyl-, alkenyl-, alkynyl-, and phenyl-substituted trans-epoxides from aldehydes. This methodology has also been applied in concise and high-yielding syntheses of both trans-epoxide containing insect sex pheromones"
Keywords:"Aldehydes/chemistry Epoxy Compounds/*chemical synthesis/chemistry Fatty Acids, Unsaturated/*chemical synthesis/chemistry Molecular Structure Sex Attractants/*chemical synthesis/chemistry Stereoisomerism;"
Notes:"MedlineKang, Baldip Britton, Robert eng Research Support, Non-U.S. Gov't 2007/11/03 Org Lett. 2007 Nov 22; 9(24):5083-6. doi: 10.1021/ol702273n. Epub 2007 Nov 2"

 
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