Title: | "Synthesis of (3E, 5Z)-3,5-dodecadienylacetate, the sex pheromone of Phtheochroa cranaodes (Lepidoptera: Tortricidae" |
Address: | "Pheromone Laboratory, Organic Division-I, Indian Institute of Chemical Technology, Hyderabad, India. yadav@iict.ap.nic.in" |
Journal Title: | Biosci Biotechnol Biochem |
ISSN/ISBN: | 0916-8451 (Print) 0916-8451 (Linking) |
Abstract: | "(3E, 5Z)-3,5-Dodecadienyl acetate, the female sex pheromone of Phtheochroa cranaodes, was regio and stereo-selectively synthesized from 1-octyne and (E)-4bromo-3-buten-1-ol by using Pd(PPh3)4, CuI and piperidine to afford the enyne (5). Further elaboration afforded the target pheromone. The synthetic pheromone was identified with the natural product by its MS and IR, data GLC retention time and biological activity" |
Keywords: | "Acetates/*chemical synthesis Animals Brazil Chromatography, Affinity Dodecanol/analogs & derivatives Female Mass Spectrometry Models, Chemical Moths/*physiology Sex Attractants/*chemical synthesis Spectrophotometry, Infrared Stereoisomerism;" |
Notes: | "MedlineYadav, J S Reddy, E J eng Research Support, Non-U.S. Gov't England 2000/09/19 Biosci Biotechnol Biochem. 2000 Aug; 64(8):1726-8. doi: 10.1271/bbb.64.1726" |