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« Previous AbstractOne-Step Synthesis of Novel Renewable Vegetable Oil-Based Acrylate Prepolymers and Their Application in UV-Curable Coatings    Next AbstractSource Apportionment of Volatile Organic Compounds (VOCs) by Positive Matrix Factorization (PMF) supported by Model Simulation and Source Markers - Using Petrochemical Emissions as a Showcase »

Environ Sci Technol


Title:Recent Advances of Chlorinated Volatile Organic Compounds' Oxidation Catalyzed by Multiple Catalysts: Reasonable Adjustment of Acidity and Redox Properties
Author(s):Su Y; Fu K; Pang C; Zheng Y; Song C; Ji N; Ma D; Lu X; Liu C; Han R; Liu Q;
Address:"Tianjin Key Lab of Indoor Air Environmental Quality Control, School of Environmental Science and Technology, Tianjin University, Tianjin 300350, China. State Key Laboratory of Engines, School of Mechanical Engineering, Tianjin University, Tianjin 300350, China"
Journal Title:Environ Sci Technol
Year:2022
Volume:20220530
Issue:14
Page Number:9854 - 9871
DOI: 10.1021/acs.est.2c01420
ISSN/ISBN:1520-5851 (Electronic) 0013-936X (Linking)
Abstract:"The severe hazard of chlorinated volatile organic compounds (CVOCs) to human health and the natural environment makes their abatement technology a key topic of global environmental research. Due to the existence of Cl, the byproducts of CVOCs in the catalytic combustion process are complex and toxic, and the possible generation of dioxin becomes a potential risk to the environment. Well-qualified CVOC catalysts should process favorable low-temperature catalytic oxidation ability, excellent selectivity, and good resistance to poisoning, which are governed by the reasonable adjustment of acidity and redox properties. This review overviews the application of different types of multicomponent catalysts, that is, supported noble metal catalysts, transition metal oxide/zeolite catalysts, composite transition metal oxide catalysts, and acid-modified catalysts, for CVOC degradation from the perspective of balance between acidity and redox properties. This review also highlights the synergistic degradation of CVOCs and NO(x) from the perspective of acidity and redox properties. We expect this work to inspire and guide researchers from both the academic and industrial communities and help pave the way for breakthroughs in fundamental research and industrial applications in this field"
Keywords:Catalysis Humans Metals Oxidation-Reduction Oxides *Volatile Organic Compounds CVOCs acidity catalytic oxidation multiple catalysts redox properties;
Notes:"MedlineSu, Yun Fu, Kaixuan Pang, Caihong Zheng, Yanfei Song, Chunfeng Ji, Na Ma, Degang Lu, Xuebin Liu, Caixia Han, Rui Liu, Qingling eng Research Support, Non-U.S. Gov't Review 2022/06/01 Environ Sci Technol. 2022 Jul 19; 56(14):9854-9871. doi: 10.1021/acs.est.2c01420. Epub 2022 May 30"

 
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