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J Org Chem


Title:Stereodivergent synthesis of (+)- and (-)-isolineatin
Author(s):Perez L; Alibes R; de March P; Busque F; Figueredo M; Font J;
Address:"Departament de Quimica, Universitat Autonoma de Barcelona, 08193 Bellaterra, Spain"
Journal Title:J Org Chem
Year:2013
Volume:20130422
Issue:9
Page Number:4483 - 4489
DOI: 10.1021/jo400487y
ISSN/ISBN:1520-6904 (Electronic) 0022-3263 (Linking)
Abstract:A stereodivergent approach to (+)- and (-)-isolineatin using (S)-4-methyl-5-pivaloyloxymethyl-2(5H)-furanone as the single source of asymmetry by exploiting the inherent chirality at the C-5 stereocenter is described
Keywords:Furans/*chemistry Magnetic Resonance Spectroscopy Molecular Structure Pheromones/*chemical synthesis/chemistry Pyrans/*chemical synthesis/chemistry Stereoisomerism;
Notes:"MedlinePerez, Laura Alibes, Ramon de March, Pedro Busque, Felix Figueredo, Marta Font, Josep eng Research Support, Non-U.S. Gov't 2013/04/16 J Org Chem. 2013 May 3; 78(9):4483-9. doi: 10.1021/jo400487y. Epub 2013 Apr 22"

 
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