| Title: | Volatile organic compound analysis of accelerant detection canine distractor odours |
| Author(s): | Leung D; Forbes S; Maynard P; |
| Address: | "University of Technology Sydney, Centre for Forensic Science, Broadway 2007 Australia. University of Technology Sydney, Centre for Forensic Science, Broadway 2007 Australia; Universite du Quebec a Trois-Rivieres, Department de Chimie, Biochimie et Physique, Trois-Rivieres G8Z 4M3 Canada. University of Technology Sydney, Centre for Forensic Science, Broadway 2007 Australia. Electronic address: Philip.Maynard@uts.edu.au" |
| DOI: | 10.1016/j.forsciint.2019.109953 |
| ISSN/ISBN: | 1872-6283 (Electronic) 0379-0738 (Linking) |
| Abstract: | "Ignitable liquid detection dogs have been observed to falsely-respond to the pyrolysis products of common burned household items such as carpets and garden hoses, where ignitable liquids were not present. These responses from the canines are described as coming from distractor odours and decrease the reliability of detector dogs. The purpose of this research was to study the volatile organic compounds (VOCs) present in the odour profile of pyrolysed carpet and garden hose substrates, and determine whether a chemical similarity exists between these pyrolysis headspace profiles and target ignitable liquids, which may explain the false-positive behaviour of these detector dogs. Garden hose and carpet samples obtained from domestic settings were heated at a constant temperature for a specified time to produce pyrolysis products. A solid-phase microextraction (SPME) method was developed to extract the VOCs from burned substrates. The odours of the burned substrates were analysed by gas chromatography-mass spectrometry (GC/MS) and gas chromatography-tandem mass spectrometry (GC/MS/MS). A GC-MS/MS method was developed targeting the characteristic aromatic compounds in gasoline. Each pyrolysed substrate produced a complex and unresolved odour profile when analysed by GC- MS. GC-MS analysis failed to find any similarities between the odours of the burned substrates and ignitable liquids. GC-MS/MS analysis of pyrolysed garden hose and carpet substrate odours resolved and identified a wide range of aromatic target compounds - and these were present in high abundances in the hose samples. This indicates that there are significant chemical similarities between vapours of ignitable liquids and their distractor odours, which will have implications for the training of ignitable liquid detector dogs" |
| Keywords: | Animals Dogs/*physiology *Fires Forensic Sciences Gas Chromatography-Mass Spectrometry *Odorants Smell/*physiology Volatile Organic Compounds/*analysis Distractor odours Gc/ms/ms Ignitable liquid detection canines Pyrolysis Volatile organic compounds; |
| Notes: | "MedlineLeung, Douglas Forbes, Shari Maynard, Philip eng Ireland 2019/09/24 Forensic Sci Int. 2019 Oct; 303:109953. doi: 10.1016/j.forsciint.2019.109953. Epub 2019 Sep 12" |
