Title: | A new green approach for Lavandula stoechas aroma recovery and stabilization coupling supercritical CO(2) and natural deep eutectic solvents |
Author(s): | Vladic J; Kovacevic S; Rebocho S; Paiva A; Jokic S; Duarte AR; Jerkovic I; |
Address: | "Faculdade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2829-516, Caparica, Portugal. Faculty of Technology, University of Novi Sad, Novi Sad, 21000, Serbia. Faculty of Food Technology Osijek, University of Josip Juraj Strossmayer of Osijek, 31000, Osijek, Croatia. Faculdade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2829-516, Caparica, Portugal. ard08968@fct.unl.pt. Faculty of Chemistry and Technology, University of Split, 21000, Split, Croatia. igor@ktf-split.hr" |
DOI: | 10.1038/s41598-023-39516-5 |
ISSN/ISBN: | 2045-2322 (Electronic) 2045-2322 (Linking) |
Abstract: | "This work investigated a green approach to obtain and stabilize Lavandula stoechas L. volatile organic compounds with sensory aroma characteristics by using alternative solvents, namely supercritical carbon dioxide (scCO(2)) and deep eutectic solvents (DES). The CO(2) extracts were dispersed in different DES mixtures (betaine:ethylene glycol (1:3), betaine:glycerol (1:2), and glycerol:glucose (4:1)) and their stability was monitored during 6 months of storage at room temperature by monitoring the headspace (HS) profile. The CO(2) extract was used as the control. It was initially determined that there was a dominant presence of oxygenated monoterpenes (67.33-77.50%) in the extracts. During storage, significant changes occurred in the samples' HS, such as the decrease in terpene hydrocarbons which also affected the presence of oxygenated terpenes, which increased in certain cases. Moreover, the highest formation of new components was recorded in the control which could be an indicator of decreased stability. The DESs-CO(2) were more stable than the CO(2) control and among them, betaine:ethylene glycol stood out as the most adequate systems for maintaining the stability of L. stoechas HS components. For the visual estimation of similarities and dissimilarities among the samples, chemometric pattern recognition approaches were applied including the hierarchical cluster analysis, principal component analysis, and sum of ranking differences" |
Notes: | "PubMed-not-MEDLINEVladic, Jelena Kovacevic, Strahinja Rebocho, Silvia Paiva, Alexandre Jokic, Stela Duarte, Ana Rita Jerkovic, Igor eng 101003396/HORIZON EUROPE Marie Sklodowska-Curie Actions/ England 2023/08/02 Sci Rep. 2023 Aug 1; 13(1):12443. doi: 10.1038/s41598-023-39516-5" |