| Title: | "New Ceramics Precursors Containing Si and Ge Atoms-Cubic Germasilsesquioxanes-Synthesis, Thermal Decomposition and Spectroscopic Analysis" |
| Author(s): | Skoczen A; Frackowiak D; Przekop RE; Frydrych M; Kasperkowiak M; Jelen P; Sitarz M; Marciniec B; |
| Address: | "Faculty of Chemistry, Adam Mickiewicz University in Poznan, Uniwersytetu Poznanskiego 8, 61-614 Poznan, Poland. Centre for Advanced Technologies, Adam Mickiewicz University in Poznan, Uniwersytetu Poznanskiego 10, 61-614 Poznan, Poland. Faculty of Materials Science and Ceramics, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Krakow, Poland" |
| DOI: | 10.3390/molecules27041441 |
| ISSN/ISBN: | 1420-3049 (Electronic) 1420-3049 (Linking) |
| Abstract: | Compounds of the silsesquioxane type are attractive material precursors. High molecular weights and well-defined structures predestine them to create ceramics with a controlled composition at the molecular level. New molecular precursors of ceramic materials with the ratio of Si:Ge = 7:1 atoms were obtained. The influence of organic substituents on the thermal decomposition processes of germasilsesquioxanes was investigated. Some of the structures obtained are characterized by a high non-volatile residue after the thermal decomposition process. The introduction of the germanium atom to the structure of the silsesquioxane molecular cage reduces the thermal stability of the obtained structures |
| Keywords: | Ft-ir Poss Raman spectroscopy ceramics precursors decomposition germasilsesquioxanes silsesquioxanes sublimation thermal analysis; |
| Notes: | "PubMed-not-MEDLINESkoczen, Aleksandra Frackowiak, Dawid Przekop, Robert E Frydrych, Milosz Kasperkowiak, Malgorzata Jelen, Piotr Sitarz, Maciej Marciniec, Bogdan eng Switzerland 2022/02/26 Molecules. 2022 Feb 21; 27(4):1441. doi: 10.3390/molecules27041441" |
