Title: | Electrochemical removal of gaseous benzene using a flow-through reactor with efficient and ultra-stable titanium suboxide/titanium-foam anode at ambient temperature |
Author(s): | Quan F; Wu B; Guo Y; Zhang X; Shen W; Jia F; Liu X; Ai Z; Zhang L; |
Address: | "College of Chemistry, Central China Normal University, Wuhan 430079, PR China; College of Chemical and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023, PR China. College of Chemistry, Central China Normal University, Wuhan 430079, PR China. College of Chemical and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023, PR China. College of Chemistry, Central China Normal University, Wuhan 430079, PR China. Electronic address: fljia@ccnu.edu.cn. College of Chemistry, Central China Normal University, Wuhan 430079, PR China. Electronic address: liuxiao71@ccnu.edu.cn" |
DOI: | 10.1016/j.jcis.2023.04.160 |
ISSN/ISBN: | 1095-7103 (Electronic) 0021-9797 (Linking) |
Abstract: | "Catalytic oxidation technology is currently considered as a feasible approach to degrade and mineralize volatile organic compounds (VOCs). However, it is still challenging to realize efficient removal of VOCs through catalytic oxidation at room temperature. In our study, a novel flow-through electrocatalytic reactor was designed, composed of porous solid-electrolyte, gas-permeable titanium sub-oxides/titanium-foam (TiSO/Ti-foam) as anode and platinum coated titanium foam (Pt/Ti-foam) as cathode. This device could oxidize nearly 100% of benzene (10 ppm) to carbon dioxide at a current density of 1.2 mA/cm(2) under room temperature. More importantly, the device maintained excellent stability over 1000 h. Mechanism of benzene mineralization was discussed. Hydroxyl radicals generated on the TiSO/Ti-foam anode played a crucial role in the oxidation of benzene. This study provides a promising prototype of the electrochemical air purifier, and may find its application in domestic and industrial air pollution control" |
Keywords: | Benzene oxidation Electrochemical removal Flow-through reactor Solid electrolyte Titanium sub-oxide; |
Notes: | "PubMed-not-MEDLINEQuan, Fengjiao Wu, Bin Guo, Yuxiao Zhang, Xu Shen, Wenjuan Jia, Falong Liu, Xiao Ai, Zhihui Zhang, Lizhi eng 2023/05/10 J Colloid Interface Sci. 2023 Sep; 645:533-541. doi: 10.1016/j.jcis.2023.04.160. Epub 2023 May 2" |