Title: | Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters |
Author(s): | Salini PS; Derry Holaday MG; Reddy ML; Suresh CH; Srinivasan A; |
Address: | "Photosciences and Photonics Group, Chemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (NIIST), Trivandrum 695 019, Kerala, India" |
ISSN/ISBN: | 1364-548X (Electronic) 1359-7345 (Linking) |
Abstract: | "Fluorine interaction assisted AIEE characteristic in an expanded calixbenzophyrin is presented by single-crystal X-ray-diffraction analysis and molecular modelling approaches. Selective exposure to volatile organic compounds such as ketones and esters results in the breaking of fluorine interaction, leading to enhanced monomer emission" |
Keywords: | "Calixarenes/*chemistry Crystallography, X-Ray Esters/*chemistry Fluorine/*chemistry Ketones/*chemistry *Luminescence Models, Molecular Molecular Structure Porphyrins/*chemistry;" |
Notes: | "MedlineSalini, P S Derry Holaday, M G Reddy, M L P Suresh, C H Srinivasan, A eng Research Support, Non-U.S. Gov't England 2013/02/09 Chem Commun (Camb). 2013 Mar 18; 49(22):2213-5. doi: 10.1039/c3cc38723b" |