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Polymers (Basel)

Title:		Eight-Fold Interpenetrating Diamondoid Coordination Polymers for Sensing Volatile Organic Compounds and Metal Ions
Author(s):		Lakshmanan V; Lai YT; Yang XK; Govindaraj M; Lin CH; Chen JD;
Address:		"Department of Chemistry, Chung-Yuan Christian University, Chung Li 32023, Taiwan. Department of Chemistry, National Taiwan Normal University, Taipei 11677, Taiwan"
Journal Title:		Polymers (Basel)
Year:		2021
Volume:		20210907
Issue:		18
Page Number:		-
DOI:		10.3390/polym13183018
ISSN/ISBN:		2073-4360 (Electronic) 2073-4360 (Linking)
Abstract:		"Reactions of divalent metal salts with 4,4-oxybis(N-(pyridine-4-yl)-benzamide), L, and naphthalene-1,4-dicarboxylic acid (1,4-H(2)NDC) in various solvents gave [Zn(L)(1,4-NDC).H(2)O](n), 1, [Cd(L)(1,4-NDC)(H(2)O).MeOH](n), 2, and [Co(L)(1,4-NDC)(H(2)O)(0.5).MeOH](n), 3, which have been structurally characterized. Complexes 1-3 show eight-fold interpenetrating frameworks with the dia topology, which exhibit porosities substantiated by CO(2) adsorption, whereas 1 and 2 manifest stability in aqueous environments and show high selectivity toward sensing of mesitylene molecules and Fe(3+) ions with low detection limits and good reusability up to five cycles"
Keywords:		coordination polymer crystal structure analysis entanglement luminescence;
Notes:		"PubMed-not-MEDLINELakshmanan, Venkatesan Lai, Yi-Ting Yang, Xiang-Kai Govindaraj, Manivannan Lin, Chia-Her Chen, Jhy-Der eng MOST 109-2113-M-033-009/Ministry of Science and Technology, Taiwan/ Switzerland 2021/09/29 Polymers (Basel). 2021 Sep 7; 13(18):3018. doi: 10.3390/polym13183018"