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J Chem Ecol


Title:Correlation of retention times on liquid crystal capillary column with reported vapor pressures and half-lives of compounds used in pheromone formulations
Author(s):Heath RR; Tumlinson JH;
Address:"U.S. Department of Agriculture, Insect Attractants, Behavior, and Basic Biology Research Laboratory Agricultural Research Service, 32604, Gainesville, Florida"
Journal Title:J Chem Ecol
Year:1986
Volume:12
Issue:11
Page Number:2081 - 2088
DOI: 10.1007/BF01041998
ISSN/ISBN:0098-0331 (Print) 0098-0331 (Linking)
Abstract:"A method has been developed to determine by capillary gas chromatography on liquid crystal stationary phases the relative vapor pressures and half-lives of many compounds used as insect pheromones. This study demonstrated that the retention time of seven acetates on a liquid crystal column (cholesteryl-p-chlorocinnamate) could be correlated closely to the reported vapor pressures of the compounds. For 13 additional pheromonal acetates and alcohols, reported half-lives showed a high degree of correlation with their retention times on the liquid crystal column. Thus chromatography on capillary liquid crystal gas Chromatographie columns appears to be a useful method for determining the relative volatilities of many pheromones to facilitate the development of more precise formulations"
Keywords:
Notes:"PubMed-not-MEDLINEHeath, R R Tumlinson, J H eng 1986/11/01 J Chem Ecol. 1986 Nov; 12(11):2081-8. doi: 10.1007/BF01041998"

 
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