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J Air Waste Manag Assoc


Title:Pilot-Scale Demonstration of an Innovative Treatment for Vapor Emissions
Author(s):Watt AS; Magrini KA; Carlson LE; Wolfrum EJ; Larson SA; Roth C; Glatzmaier GC;
Address:"a National Renewable Energy Laboratory , Golden , Colorado , USA"
Journal Title:J Air Waste Manag Assoc
Year:1999
Volume:49
Issue:11
Page Number:1368 - 1373
DOI: 10.1080/10473289.1999.10463968
ISSN/ISBN:2162-2906 (Electronic) 1096-2247 (Linking)
Abstract:"Researchers from the National Renewable Energy Laboratory recently conducted a pilot-scale study at McClellan Air Force Base (AFB) in Sacramento, CA. The objective of the test was to determine the effectiveness of an ambient-temperature, solar-powered photocatalytic oxidation treatment unit for destroying emissions of chlorinated organic compounds from an air stripper. This paper reports test results and discusses applications and limitations of the technology. A 10-standard-cubic-foot-per-minute (SCFM) (28.3 L/min) slip stream of air from an air stripper at Operative Unit 29-31 at McClellan AFB was passed through a reactor that contained a lightweight, perforated, inert support coated with photoactive titanium dioxide. The reactor faced south and was tilted at a 45 degrees angle from vertical so that the light-activated catalyst received most of the available sunlight. An online portable gas chro-matograph with two identical columns simultaneously analyzed the volatile organic compounds contained in the reactor inlet and outlet air streams. Summa canister grab samples of the inlet and outlet were also collected and sent to a certified laboratory for U.S. Environmental Protection Agency Method TO-14 analysis and verification of our field analyses. Three weeks of testing demonstrated that the treatment system's destruction and removal efficiencies (DREs) are greater than 95% at 10 SCFM with UV intensities at or greater than 1.5 milliwatts/square centimeter (mW/cm(2)). DREs greater than 95% at 20 SCFM were obtained under conditions where UV irradiation measured at or greater than 2 mW/cm(2). In Sacramento, this provided 6 hours of operation per clear or nearly clear day in April. A solar tracking system could extend operating time. The air stream also contained trace amounts of benzene. We observed no loss of system performance during testing"
Keywords:
Notes:"PubMed-not-MEDLINEWatt, Andrew S Magrini, Kimberly A Carlson, Lynnae E Wolfrum, Edward J Larson, Sheldon A Roth, Christine Glatzmaier, Greg C eng 1999/11/01 J Air Waste Manag Assoc. 1999 Nov; 49(11):1368-1373. doi: 10.1080/10473289.1999.10463968"

 
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