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J Agric Food Chem


Title:"Quantitation of Key Aroma Compounds in Fresh, Raw Ginger (Zingiber officinale Roscoe) from China and Roasted Ginger by Stable Isotope Dilution Assays and Aroma Profiling by Recombination Experiments"
Author(s):Schaller T; Schieberle P;
Address:"Deutsche Forschungsanstalt fur Lebensmittelchemie (now Leibniz Institute for Food Systems Biology at the TU Munich), Lise-Meitner-Strasse 34, D-85354 Freising, Germany. Faculty of Chemistry, Technical University of Munich, Lichtenbergstrasse 4, 85748 Garching, Germany"
Journal Title:J Agric Food Chem
Year:2020
Volume:20201210
Issue:51
Page Number:15284 - 15291
DOI: 10.1021/acs.jafc.0c06733
ISSN/ISBN:1520-5118 (Electronic) 0021-8561 (Linking)
Abstract:"Twenty key odorants recently identified in raw and roasted ginger were quantitated by means of stable isotope dilution assays, of which six assays were newly developed. Odor activity values (OAV; ratio of concentration to odor threshold) revealed 1,8-cineol (eucalyptus-like) with by far the highest value of 65?ª+000 followed by myrcene (geranium-like), for which an OAV of 19?ª+000 was calculated. In addition, (R)-citronellal, geranial, (R)-linalool, (E)-isoeugenol, and (E)-2-octenal contributed with high OAVs to the overall aroma profile of the fresh, raw ginger. An aroma recombinate prepared with 20 reference compounds in the same concentrations as determined in the ginger sample successfully matched the overall aroma profile. In the roasted ginger, 1,8-cineol and myrcene remained the most odor-active compounds, however, the increase in some odorants, for example, in geraniol and (Z)-2-decenal, in combination with the newly formed caramel-like smelling 4-hydroxy-2,5-dimethyl-3(2H)-furanone (caramel-like) and 3-(methylthio)propanal (potato-like) most likely caused the differences in the aroma profile initiated by the thermal treatment. A biomimetic aroma recombinate based on 21 aroma compounds was able to successfully simulate the aroma profile of the roasted ginger"
Keywords:Carbon Isotopes/analysis China Cooking Gas Chromatography-Mass Spectrometry Ginger/*chemistry Hot Temperature Humans Molecular Structure Odorants/analysis Plant Tubers/chemistry Smell Volatile Organic Compounds/*chemistry [13C2]-geranial [13C2]-neral [2H2;
Notes:"MedlineSchaller, Tanja Schieberle, Peter eng Comparative Study 2020/12/11 J Agric Food Chem. 2020 Dec 23; 68(51):15284-15291. doi: 10.1021/acs.jafc.0c06733. Epub 2020 Dec 10"

 
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