Title: | Synthesis and field tests of possible minor components of the sex pheromone of Prionus californicus |
Author(s): | Maki EC; Rodstein J; Millar JG; Barbour KS; Hanks LM; Barbour JD; |
Address: | "Southwest Idaho Research & Extension Center, Parma, ID 83660-9637, USA" |
DOI: | 10.1007/s10886-011-9972-x |
ISSN/ISBN: | 1573-1561 (Electronic) 0098-0331 (Linking) |
Abstract: | "Earlier work has shown that adult male Prionus californicus Motschulsky (Coleoptera: Cerambycidae) are attracted to the female-produced compound (3R,5S)-3,5-dimethyldodecanoic acid, and to a synthetic mixture of the four stereoisomers of 3,5-dimethyldodecanoic acid. Here, we report the results of field trials that tested whether or not three structurally related compounds (methyl 3,5-dimethyldodecanoate, 3,5-dimethyltridecanoic acid, and 3,5-dimethylpentadecanoic acid), present in extracts of virgin females, are attractive, and whether or not they influence attraction to 3,5-dimethyldodecanoic acid. In a trial with single components, only traps baited with the acid or its methyl ester captured more beetles than did control traps; catches to the acid were five times higher than to the methyl ester. Another trial, excluding 3,5-dimethyldodecanoic acid, confirmed the activity of the methyl ester. Finally, addition of the three compounds to 3,5-dimethyldodecanoic acid, in the ratio found in extracts from female beetles, gave a catch similar to that of traps baited with 3,5-dimethyldodecanoic acid alone. Consequently, the function of these minor compounds remains undetermined" |
Keywords: | "Animals Chromatography, Gas Coleoptera/*chemistry *Decanoic Acids/chemical synthesis/metabolism Female Male Sex Attractants/chemical synthesis/*chemistry/metabolism Solid Phase Microextraction Stereoisomerism;" |
Notes: | "MedlineMaki, Elin C Rodstein, Joshua Millar, Jocelyn G Barbour, Karen S Hanks, Lawrence M Barbour, James D eng Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. 2011/06/02 J Chem Ecol. 2011 Jul; 37(7):714-6. doi: 10.1007/s10886-011-9972-x. Epub 2011 May 27" |