Title: | Phytovolatilization of Organic Contaminants |
Address: | "University of Delaware , Department of Plant & Soil Sciences, Newark, Delaware 19716, United States. Missouri University of Science and Technology , Department of Civil, Architectural and Environmental Engineering, Rolla, Missouri 65409, United States" |
ISSN/ISBN: | 1520-5851 (Electronic) 0013-936X (Linking) |
Abstract: | "Plants can interact with a variety of organic compounds, and thereby affect the fate and transport of many environmental contaminants. Volatile organic compounds may be volatilized from stems or leaves (direct phytovolatilization) or from soil due to plant root activities (indirect phytovolatilization). Fluxes of contaminants volatilizing from plants are important across scales ranging from local contaminant spills to global fluxes of methane emanating from ecosystems biochemically reducing organic carbon. In this article past studies are reviewed to clearly differentiate between direct- and indirect-phytovolatilization and we discuss the plant physiology driving phytovolatilization in different ecosystems. Current measurement techniques are also described, including common difficulties in experimental design. We also discuss reports of phytovolatilization in the literature, finding that compounds with low octanol-air partitioning coefficients are more likely to be phytovolatilized (log KOA < 5). Reports of direct phytovolatilization at field sites compare favorably to model predictions. Finally, future research needs are presented that could better quantify phytovolatilization fluxes at field scale" |
Keywords: | Ecosystem Plant Roots Plants *Soil *Soil Pollutants; |
Notes: | "MedlineLimmer, Matt Burken, Joel eng Review 2016/06/02 Environ Sci Technol. 2016 Jul 5; 50(13):6632-43. doi: 10.1021/acs.est.5b04113. Epub 2016 Jun 16" |