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J Hazard Mater


Title:"Visible light promoted degradation of gaseous volatile organic compounds catalyzed by Au supported layered double hydroxides: Influencing factors, kinetics and mechanism"
Author(s):Fu S; Zheng Y; Zhou X; Ni Z; Xia S;
Address:"College of Water Conservancy and Hydropower Engineering, Hohai University, 1 Xikang Road, Nanjing, 210024, PR China. Entegris, Inc., 129 Concord Road, Billerica, MA, 01821, USA. Department of Chemistry, College of Chemical Engineering, Zhejiang University of Technology, 18 Chaowang Road, Hangzhou, 310014, PR China. Department of Chemistry, College of Chemical Engineering, Zhejiang University of Technology, 18 Chaowang Road, Hangzhou, 310014, PR China. Electronic address: xiasj@zjut.edu.cn"
Journal Title:J Hazard Mater
Year:2019
Volume:20181004
Issue:
Page Number:41 - 54
DOI: 10.1016/j.jhazmat.2018.10.009
ISSN/ISBN:1873-3336 (Electronic) 0304-3894 (Linking)
Abstract:"In this paper, factors of initial concentration, catalyst dosage, irradiation intensity, relative humidity and reaction temperature onto visible light gaseous o-xylene photodegradation by ZnCr layered double hydroxides (ZnCr-LDHs) and Au supported ZnCr-LDHs (Au/ZnCr-LDHs) were investigated. ZnCr-LDHs shows low removal efficiency for o-xylene photodegradation, while Au/ZnCr-LDHs exhibits both excellent photodegradation rate and high TOF values for o-xylene as well as other VOCs including benzene, o-xylene, m-xylene and p-xylene. The kinetic equation and activation energy were calculated for o-xylene photodegradation, which are [Formula: see text] and 21.85 kJ/mol for ZnCr-LDH [Formula: see text] and 12.84 kJ/mol for Au/ZnCr-LDHs. The obvious difference both in kinetic equation and activation energy suggests the reaction mechanism of ZnCr-LDHs and Au/ZnCr-LDHs should be very different. The active species inhabitation experiments show that the major drive of photocatalytic reaction for ZnCr-LDHs is hydroxyl radical, while for Au/ZnCr-LDHs it is the hole and hydroxide radical. It is also proved that the support of Au NPs onto LDHs would result in the transfer of photoexcited electrons from LDHs to Au NPs which results in the enhancement of photocatalytic property as well as photocatalytic mechanism change based on UV-vis, XPS, the contribution of different wavelength ranges of visible light onto photocatalytic efficiency and electrochemical tests"
Keywords:Au supported layered double hydroxides Electron transfer Kinetic and mechanism Photodegradation Volatile organic compounds (VOCs);
Notes:"PubMed-not-MEDLINEFu, Shifeng Zheng, Yuan Zhou, Xiaobo Ni, Zheming Xia, Shengjie eng Netherlands 2018/10/10 J Hazard Mater. 2019 Feb 5; 363:41-54. doi: 10.1016/j.jhazmat.2018.10.009. Epub 2018 Oct 4"

 
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