Title: | "Synthesis of the racemate of (Z)-exo-alpha-bergamotenal, a pheromone component of the white-spotted spined bug, Eysarcoris parvus Uhler" |
Author(s): | Alizadeh BH; Kuwahara S; Leal WS; Men HC; |
Address: | "Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultural Science, Tohoku University, Sendai, Japan" |
Journal Title: | Biosci Biotechnol Biochem |
ISSN/ISBN: | 0916-8451 (Print) 0916-8451 (Linking) |
Abstract: | "The racemate of (Z)-exo-alpha-bergamotenal, a sex pheromone component of the white-spotted spined bug, was synthesized from racemic exo-alpha-bergamotene by a five-step sequence involving regioselective epoxidation and (Z)-selective Wittig olefination reactions. The 1H- and 13C-NMR spectra of the synthetic sample were identical with those of the natural material" |
Keywords: | "Animals Insecta/*chemistry Magnetic Resonance Spectroscopy Molecular Structure Pentanols/*chemical synthesis/chemistry Sesquiterpenes/*chemical synthesis/chemistry Sex Attractants/*chemical synthesis/chemistry Spectrophotometry, Infrared;" |
Notes: | "MedlineAlizadeh, Babak Heidary Kuwahara, Shigefumi Leal, Walter Soares Men, Hong-Chao eng Research Support, Non-U.S. Gov't England 2002/08/07 Biosci Biotechnol Biochem. 2002 Jun; 66(6):1415-8. doi: 10.1271/bbb.66.1415" |