Title: | Chemoenzymatic synthesis of the alarm pheromone (+)-verbenone from geranyl diphosphate |
Author(s): | Yoosuf-Aly Z; Faraldos JA; Miller DJ; Allemann RK; |
Address: | "School of Chemistry and Cardiff Catalysis Institute, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, United Kingdom" |
ISSN/ISBN: | 1364-548X (Electronic) 1359-7345 (Linking) |
Abstract: | "The enzyme-guided asymmetric synthesis of (+)-verbenone from geranyl diphosphate in a simple two-step, one pot transformation highlights the potential of chemoenzymatic procedures for the generation of high-value terpenoids" |
Keywords: | Bicyclic Monoterpenes Cyclization Diphosphates/chemistry/*metabolism Diterpenes/chemistry/*metabolism Intramolecular Lyases/chemistry/*metabolism Molecular Structure Stereoisomerism Terpenes/chemistry/*metabolism; |
Notes: | "MedlineYoosuf-Aly, Zulfa Faraldos, Juan A Miller, David J Allemann, Rudolf K eng BB/G003572/1/Biotechnology and Biological Sciences Research Council/United Kingdom BB/H01683X/1/Biotechnology and Biological Sciences Research Council/United Kingdom Research Support, Non-U.S. Gov't England 2012/06/12 Chem Commun (Camb). 2012 Jul 18; 48(56):7040-2. doi: 10.1039/c2cc32883f. Epub 2012 Jun 11" |