Title: | "A non-iterative, flexible, and highly stereoselective synthesis of polydeoxypropionates--synthesis of (+)-vittatalactone" |
Author(s): | Weise CF; Pischl M; Pfaltz A; Schneider C; |
Address: | "Institut fur Organische Chemie, Universitat Leipzig, Johannisallee 29, D-04103 Leipzig, Germany" |
ISSN/ISBN: | 1364-548X (Electronic) 1359-7345 (Linking) |
Abstract: | "A short sequence comprising an oxy-Cope rearrangement, iridium-catalyzed hydrogenation, and enolate methylation provides trideoxypropionates with excellent diastereocontrol. A straightforward synthesis of the cucumber beetle pheromone (+)-vittatalactone illustrates this new strategy" |
Keywords: | Animals Catalysis Coleoptera/chemistry Hydrogenation Iridium/chemistry Lactones/*chemical synthesis/chemistry Pheromones/chemistry Stereoisomerism; |
Notes: | "MedlineWeise, Christian F Pischl, Matthias Pfaltz, Andreas Schneider, Christoph eng Research Support, Non-U.S. Gov't England 2011/02/01 Chem Commun (Camb). 2011 Mar 21; 47(11):3248-50. doi: 10.1039/c0cc05215a. Epub 2011 Jan 28" |