Title: | "A green triple-locked strategy based on volatile-compound imaging, chemometrics, and markers to discriminate winter honey and sapium honey using headspace gas chromatography-ion mobility spectrometry" |
Author(s): | Wang X; Yang S; He J; Chen L; Zhang J; Jin Y; Zhou J; Zhang Y; |
Address: | "Institute of Apicultural Research, Chinese Academy of Agricultural Sciences, Beijing 100093, PR China. Institute of Apicultural Research, Chinese Academy of Agricultural Sciences, Beijing 100093, PR China; Laboratory of Risk Assessment for Quality and Safety of Bee Products, Ministry of Agriculture, Beijing 100093, PR China; Key Laboratory of Bee Products for Quality and Safety Control, Ministry of Agriculture, Beijing 100093, PR China; Bee Product Quality Supervision and Testing Centre, Ministry of Agriculture, Beijing 100093, PR China. Shandong Hanon Scientific Instruments Co., Ltd, Jinan 250101, PR China. Institute of Apicultural Research, Chinese Academy of Agricultural Sciences, Beijing 100093, PR China; Laboratory of Risk Assessment for Quality and Safety of Bee Products, Ministry of Agriculture, Beijing 100093, PR China; Key Laboratory of Bee Products for Quality and Safety Control, Ministry of Agriculture, Beijing 100093, PR China; Bee Product Quality Supervision and Testing Centre, Ministry of Agriculture, Beijing 100093, PR China. Electronic address: zhoujinhui@caas.cn. Institute of Chinese Materia Medica, China Academy of Chinese Medical Sciences, Beijing 100700, PR China. Electronic address: snonxin@126.com" |
DOI: | 10.1016/j.foodres.2019.01.004 |
ISSN/ISBN: | 1873-7145 (Electronic) 0963-9969 (Linking) |
Abstract: | "A simple and environmentally approach using untargeted imaging of volatile substances combined with chemometrics and markers response was proposed for discriminating different species of honey with headspace gas-chromatography-ion-mobility (HS-GC-IMS). The 3D HS-GC-IMS imaging and their response differences enabled the clear discrimination between winter honey and sapium honey. Principal component analysis (PCA) and partial least-squares discrimination analysis (PLS-DA) were employed to discriminate different honey. Markers of two kinds of honey were identified and confirmed with a user-built imaging database combined with multivariate analysis. Benzaldehyde dimer and phenylacetaldehyde dimer were found to be reliable markers of winter honey, and phenylethyl acetate dimer was of sapium honey. Adulteration identification of the honey samples with different adulteration ratios were subjected to this triple-locked strategy analysis. The results demonstrate that HS-GC-IMS imaging coupled with chemometrics and marker identification is a useful triple-locked strategy to discriminate honey from different floral origins and adulterated honey" |
Keywords: | "Acetates/analysis Benzaldehydes/analysis Gas Chromatography-Mass Spectrometry/*methods Honey/*analysis Imaging, Three-Dimensional Ion Mobility Spectrometry/*methods Least-Squares Analysis Multivariate Analysis Principal Component Analysis Sapium/*chemistr;" |
Notes: | "MedlineWang, Xinran Yang, Shupeng He, Jinna Chen, Lanzhen Zhang, Jinzhen Jin, Yue Zhou, Jinhui Zhang, Yongxin eng Research Support, Non-U.S. Gov't Canada 2019/03/20 Food Res Int. 2019 May; 119:960-967. doi: 10.1016/j.foodres.2019.01.004. Epub 2019 Jan 6" |