| Title: | New application of direct analysis in real time high-resolution mass spectrometry for the untargeted analysis of fresh and aged secondary organic aerosols generated from monoterpenes |
| Author(s): | Schramm S; Zannoni N; Gros V; Tillmann R; Kiendler-Scharr A; Sarda-Esteve R; Bridoux M; |
| Address: | "LCP-A2MC, Universite de Lorraine ICPM, 1 boulevard Arago, 57078, Metz Cedex, 03, France. CEA, DRF, LSCE, F-91191, Gif-sur-Yvette, France. Institut fur Chemie und Dynamik der Geosphare 2, Forschungszentrum Julich GmbH, Julich, Germany. CEA, DAM, DIF, F-91297, Arpajon, France" |
| Journal Title: | Rapid Commun Mass Spectrom |
| ISSN/ISBN: | 1097-0231 (Electronic) 0951-4198 (Linking) |
| Abstract: | "RATIONALE: Secondary organic aerosols (SOAs) represent a significant portion of total atmospheric aerosols. They are generated by the oxidation of volatile organic compounds (VOCs), and particularly biogenic VOCs (BVOCs). The analysis of such samples is usually performed by targeted methods that often require time-consuming preparation steps that can induce loss of compounds and/or sample contaminations. METHODS: Recently, untargeted methods using high-resolution mass spectrometry (HRMS) have been successfully employed for a broad characterization of chemicals in SOAs. Herein we propose a new application of the direct analysis in real time (DART) ionization method combined with HRMS to quickly detect several hundred chemicals in SOAs collected on a quartz filter without sample preparation or separation techniques. RESULTS: The reproducibility of measurements was good, with several hundred elemental compositions common to three different replicates. The relative standard deviations of the intensities of the chemical families ranged from 6% to 35%, with sufficient sensitivity to allow the unambiguous detection of 4 ng/mm(2) of pinic acid. The presence of oligomers and specific tracers was highlighted by MS(n) (n |
| Keywords: | Aerosols/*analysis/chemistry Air Pollutants/analysis/chemistry Mass Spectrometry/*methods Monoterpenes/*analysis/chemistry Oxidation-Reduction Volatile Organic Compounds/*analysis/chemistry; |
| Notes: | "MedlineSchramm, Sebastien Zannoni, Nora Gros, Valerie Tillmann, Ralf Kiendler-Scharr, Astrid Sarda-Esteve, Roland Bridoux, Maxime eng England 2018/07/05 Rapid Commun Mass Spectrom. 2019 May; 33 Suppl 1:50-59. doi: 10.1002/rcm.8228. Epub 2018 Aug 13" |
