Title: | Enantiodivergent synthesis of both enantiomers of gypsy moth pheromone disparlure |
Address: | "Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India. prasad@orgchem.iisc.ernet.in" |
ISSN/ISBN: | 0022-3263 (Print) 0022-3263 (Linking) |
Abstract: | "Enantiodivergent synthesis of both (-)- and (+)-disparlure, a bioactive pheromone, possessing a cis-epoxide has been accomplished. The key step involves the cross metathesis of a chiral homoallylic alcohol derived from l-(+)-tartaric acid" |
Keywords: | Alkanes/*metabolism Animals Moths/*metabolism Pheromones/*metabolism Stereoisomerism; |
Notes: | "MedlinePrasad, Kavirayani R Anbarasan, Pazhamalai eng Research Support, Non-U.S. Gov't 2007/03/21 J Org Chem. 2007 Apr 13; 72(8):3155-7. doi: 10.1021/jo070060o. Epub 2007 Mar 17" |