Title: | "Enantiospecific synthesis of (3S,6R)-3-hydroxy-1,7-dioxaspiro[5.5]undecane and its (4R)-4-hydroxy isomer [minor components of olive fruit fly (Dacus oleae) sex pheromone]" |
Author(s): | Izquierdo Cubero I; Plaza Lopez-Espinosa MT; Castillo RA; |
Address: | "Department of Organic Chemistry Faculty of Pharmacy, University of Granada, 18071, Granada, Spain" |
ISSN/ISBN: | 0098-0331 (Print) 0098-0331 (Linking) |
Abstract: | "The synthesis of (3S,6R)-3-hydroxy-1,7-dioxaspiro[5.5]undecane (8) and its (4R)-4-hydroxy isomer (11) from (3R,4S,6R)-3,4-dihydroxy-1,7-dioxaspiro[5.5]undecane (1), obtained from D-fructose, has been accomplished by regioselective deoxygenation at C-4 and C-3, respectively, of the appropriately protected derivatives" |
Notes: | "PubMed-not-MEDLINEIzquierdo Cubero, I Plaza Lopez-Espinosa, M T Castillo, R A eng 1992/02/01 J Chem Ecol. 1992 Feb; 18(2):115-25. doi: 10.1007/BF00993747" |